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     Research Journal of Applied Sciences, Engineering and Technology


Glycerolysis of Glycerol Carbonate from Crude Glycerol for Synthesis of Polyurethane

1Hor Yan Phin, 2Soo King Lim, 1Chong Yu Low, 1Leong Huat Low and 1Chiu Yong Tan
1Department of Petrochemical Engineering, Faculty of Engineering and Green Technology, Universiti Tunku Abdul Rahman, 31900, Kampar, Perak, Malaysia
2Department of Electrical and Electronic Engineering, Lee Kong Chian Faculty of Engineering and Science, Universiti Tunku Abdul Rahman, Bandar Sungai Long, Cheras 43000 Kajang, Selangor, Malaysia
Research Journal of Applied Sciences, Engineering and Technology   2015  10:1144-1150
http://dx.doi.org/10.19026/rjaset.11.2129  |  © The Author(s) 2015
Received: July ‎7, ‎2015  |  Accepted: August ‎11, ‎2015  |  Published: December 05, 2015

Abstract

10% by weight of crude glycerol is produced during biofuel fermentation process, which has impacted the price of biofuel due to impurity content. In addition, the government’s regulations have prohibited the usage of crude glycerol as fuel source due to the emission of hazardous gases. This study provides the insight study of the properties and source of crude glycerol that can be converted into glycerol carbonate by glycerolysis process, where the particular glycerol carbonate is used as catalyst for synthesizing of polyurethane polymer that has a number of applications in real life. Glycerolysis process of glycerol carbonate using Pro-II 9.3 simulator is proposed and is feasible for implementation that would effectively utilize crude glycerol that is abundant in biodiesel market.

Keywords:

Biodiesel, crude glycerol, glycerol carbonate, glycerolysis process,


References


Competing interests

The authors have no competing interests.

Open Access Policy

This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.

Copyright

The authors have no competing interests.

ISSN (Online):  2040-7467
ISSN (Print):   2040-7459
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